FAQ on filtration of gaseous pollutants and odors |
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By Frank Hammes, President IQAir North America and R & D Director at Incen AG (Switzerland) |
Editor's Note: We posed these questions to the President of IQAir since our members often ask the same questions and the answers are complex.
We have added several of the IQAir line of air filtration machines
and accessories to our product line and will be adding more commercial items soon. We think you will particularly interested in the following. Are you like me in allergy season torn between fresh air and removing allergens? IQAir have solved this problem with a window intake duct which is an accessory available for every IQAir machine. It brings the fresh air [Oxygen yea!, no stuffy, stale smell] in through the duct in the window and fresh filtered air comes into your room.
We have also added the multigas Gas Control filter especially designed for control of gases/VOCS. As you might have gathered from the article above, this filter has a very different design from a regular hepa filter.
http://www.allergybuyersclubshopping.com/iqairgcseries.html
| Q. |
How
about just a quick basic education? What does one need in a
filter for odor control? Are there different grades of carbon
filter? |
| A. |
The
air we breathe contains apart from oxygen, carbon dioxide,
carbon monoxide, a few precious gases and a percentage of
humidity, a range of pollutants. These pollutants take three
physical states: solid (e.g. dust, allergens, bacteria, viruses),
liquid (e.g. mist, fog, aerosol-sprays) and gaseous (e.g.
VOCs, formaldehyde). The technology needed in an air cleaner
to remove gaseous pollutants and odors is entirely different
to that need to filter dust particles and aerosols.
While
solid and liquid particles can be effectively removed by media
filters, such as a good HEPA filter, gaseous pollutants and
odors, due to their physical state and extremely small size
(< 0.001 microns) cannot. In fact HEPA filters have 0% efficiency
for gaseous chemical compounds. These compounds simply pass
through the HEPA filter.
In
order to filter gaseous pollutants and odors effectively a
number of filter technologies exist. The most common one found
in air cleaners is activated carbon. Activated carbon consists
of a carbon structure, which has been cleaned with hot steam
to create an extremely porous structure. Like a miniscule
sponge, activated carbon contains thousands of little cracks
and pores. These are responsible for a very large internal
surface area. This surface area exerts a physical force, which
attracts many gas molecules and binds them to the surface
of the carbon. This process is called adsorption. In order
for an activated carbon filter to work effectively, there
needs to be a sufficient amount of carbon, so that the air,
which is passing through the filter is able to deposit its
pollutant molecules with the activated carbon. Coconut shell
carbon.
Activated
carbon can be used in many different forms in an air cleaner.
Most air cleaners only contain a fiber pad, which is impregnated
with a few ounces of carbon dust. This is the least effective
way to use activated carbon, because of the small amount of
carbon. Some air cleaners contain more substantial granular
activated carbon filters. Most of these air cleaners use activated
carbon made from coconut shell. While this carbon is inexpensive
and widely available some allergy sufferers have reported
to be allergic to dust from coconut shell carbon.
Coconut
carbon is also very soft and tends to generate dust during
transport and sometimes even during usage. Most systems for
professional gas and odor removal utilize activated carbon
in the shape of small pellets made from coal or peat. This
carbon is significantly harder and gives off virtually no
dust.
Another
aspect which affects the effectiveness of activated carbon
for indoor air quality issues is its degree of activation.
Most activated carbon available today is manufactured for
industrial applications, such as solvent recovery. For this
application, the carbon is activated for the maximum amount
of pores. While this increases the capacity of the activated
carbon at very high pollution concentrations, it actually
decreases its effectiveness to remove odors and chemicals
at the typical concentrations in home and office environments.
This is explained by the fact, that the higher the carbon
is activated the larger the pores become. It is, however,
only the very smallest pores in the activated carbon, called
micropores, which are capable for removing odors and chemicals
under home and office conditions. IQAir uses activated carbon
in its IQAir HealthPro Plus and its IQAir GC Series air cleaners
which is activated in a way to preserve a maximum amount of
micropores for best possible gas and odor control in homes
and offices.
When
one looks at controlling gaseous pollutants and odors in indoor
environments, it is important to realize that the right activated
carbon filters is able to deal with many gaseous pollutants
and odors, it is not suitable for all. While activated carbon
is particularly suitable for volatile organic compounds (VOCs),
such as benzene, toluene, styrene, it is not effective for
less volatile compounds, such as formaldehyde or many inorganic
gases such as hydrogen sulfide and sulfur dioxide. These compounds
require a chemical reaction to break them down. The best results,
for removing these compounds, are granular chemically active
sorbant materials, called chemisorbers. Chemisorbers consist
of aluminoxyde impregnated with potassium permanganate. When
the potassium permanganate gets in contact with humidity and
a suitable gas molecule it breaks it down to harmless CO2.
This is particularly effective for controlling formaldehyde,
hydrogen sulfide, and sulfur dioxide.
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| Q. |
How
about carbon filters mixed with Zeolite? Are they better or
worse? |
| A. |
A
number of manufacturers use a granular material called zeolite
in combination with activated carbon and claim that this is
a more effective gas filtration mix. We have found no independent
scientific evidence for this claim. In fact, zeolite is not
used in industrial or commercial air filtration, because chemisorbants
and impregnated carbons have been found to work best. The
best explanation as to why zeolite is used in residential
air cleaners is that it is even cheaper than coconut shell
activated carbon and the use of another gas phase media sounds
good to unsuspecting residential consumers.
As
important as the gas and odor filtration media chosen, is
the way in which it is used in an air cleaner to ensure best
possible gas and odor removal. It is particularly important
that gas filtration media is incorporated in a way in the
air cleaner that insures maximum contact with air being cleansed,
while ensuring that the air is restricted as little as possible.
The best way this can be done is with a V-shaped granular
media element, such as is featured in IQAir HealthPro Plus
(shipping from December 1, 2000) or by using cylindrical shaped
cartridges as in the IQAir GC Series.
Another
issue important issue to consider in how an air cleaner uses
gas phase and odor filtration media, is how well it is protected
against clogging. Since both activated carbon and chemisorbant
media relies on its fine pore structure for the removal of
gas molecules it is essential for these pores not to be clogged
by dust particles. Yet most manufacturers use carbon filters
as dust pre-filters or use low efficiency pre-filters. This
means that that gas and odor removal effectiveness decreases
rapidly with use. Some manufacturers try to work around this
by placing the activated carbon filter after the HEPA filter.
While this indeed protects the activated carbon filter it,
creates a problem for users, since any carbon dust released
by the carbon filter is not retained. IQAir has solved this
issue the same way large-scale commercial air cleaning systems
have solved it. We place a high-efficiency particulate pre-filter
ahead of the activated carbon filter and places a HEPA filter
after the activated carbon filter.
The
last item to look out for in an air cleaner with gas and odor
filters is that these can be replaced independently of HEPA
and pre- filters. HEPA filters generally last several times
longer than activated carbon filters and pre-filters have
a shorter life. If they are combined in one filter element
both need to be replaced even if only one is used up. The
IQAir HealthPro Plus contains the pre-filter, the gas phase
filter and the HEPA filter in three separately replaceable
filters. Only filters which are used up need to be replaced.
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| Q. |
We
get a number of people who are looking for a filter for their
basement. It appears that although basements are inherently
unhealthy living spaces, people want a filter to eliminate mold,
odors, and other unhealthy aspects of basement air. Your comments?
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| A. |
The
reason that basement air is considered "bad" has a number
of reasons. Basements are many times cooler and more humid
that other parts of the house. This can lead to condensation
of humidity on walls and windows, which may lead to mold growth.These
molds are not only responsible for producing mold spores,
but also a range of complex chemicals, called mycotoxins,
some of which are toxic.
Another
reason that the air in basement is "bad" is that there tends
to be less ventilation in basements as in other parts of a
house.
The
above issues of humidity and lack of ventilation should be
address by inhabitants as a first part of a strategy to improve
air quality. This can be done with dehumidification, insulation
and ventilation. An air cleaner should be used only after
the underlying sources of the problem have been addressed.
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| Q. |
What
about odors from building materials and furnishings? |
| A. |
While
all of the above odors are emitted by specific sources, e.g.
a burning cigarette, it needs to be realized that over time
secondary sources for odors may develop. These secondary sources
are caused by the deposition of odor causing substances on furnishings
or room surfaces. These act as sinks, which accumulate odor-causing
substances. An example of how this works, is when you come home
from spending an hour in a smoky bar, your clothes will start
emitting cigarette odor. While you were in the bar particles
and gas molecules will have deposited on your cloth. Back in
a clean environment odor molecules which have attached to the
cloth and the particles on your cloth will come off. |
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| Q. |
Which
filters do best in a damp environment? |
| A. |
Activated
carbon filters do badly in damp environments because the miniscule
pores in the carbon get filled with humidity molecules which
don't allow gaseous pollutant molecules to be taken up. Filters
with chemisorbant do very well in damp environments because
their chemical breakdown process of air pollutants accelerates
with increasing humidity. |
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| Q. |
I
am hearing more about people who live in smog or polluted areas,
even just car and highway fumes wafting into their apartments. |
| A. |
In
order to help prevent smog and highway fumes penetrating indoor
environments; the most effective solution is based on a two-stage
strategy. The best solution is to prevent smog and fumes from
entering in the first place. This can be done by creating a
slight overpressure (using the IQAir MultiGas GC and Inflow
W125) in the apartment by installing an air cleaning system
which is optimized for smog and traffic fumes which draws in
air from outside and filters it before releasing it into the
indoor environment. It is only the second best strategy, to
have an air cleaner that filters the air within the room by
recirculation. |
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| Q. |
What
about those people who get forest fires in their area? |
| A. |
The
same as for smog and highway fumes goes for forest fires. It
is essential to make sure that only cleaned air enters the apartment
or home, to ensure the best possible improvement in indoor air
quality. Due to the high concentrations of sulfur dioxide and
other combustion gases, we recommend the IQAir MultiGas GC,
which contains a wide spectrum gas phase control filter. |
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| Q. |
We
have club members with Multiple Chemical Sensitivity (MCS).
What kind of machine do these people need? |
| A. |
Individuals
with MCS should select an air cleaner which is capable of
effectively filtering a wide range of chemical compounds.
A good choice is an air cleaner with substantial amounts of
granular activated carbon and chemisorbant granulate. This
covers not only volatile organic compounds, but also semi-volatile
organic compounds and some inorganic compounds. Ideally, the
unit of choice should have at least 5 pounds of granular activated
carbon and chemisorbers (IQAir MultiGas GC). Make sure that
it also contains an effective particulate filter after the
granular gas filtration media, to prevent from carbon or chemisorbant
dust being emitted by the air cleaner.
Some
manufacturers have claimed that air cleaners with a metal
housing are preferable to air cleaners with a plastic housing,
due to less off-gassing. We have found that high-quality plastic
housings made from ABS (used for making personal computers),
PP or PC plastic poses no problem of off-gassing. The plastics
that pose a threat of off- gassing are plastics which contains
softening agents, such as PVC. In fact many air cleaners with
metal housing may be responsible for significant off-gassing
due to internal soft gaskets and sealing compounds that need
to be used between metal parts and filters. The unit of choice
for MCS sufferers from the IQAir product line is the IQAir
MultiGas GC due to its wide spectrum gas phase control.
http://www.allergybuyersclubshopping.com/iqairgcseries.html
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| Q. |
What
about off-gassing of furniture and carpets? |
| A. |
Furniture
made from compressed particleboard may contain significant levels
of formaldehyde, which can off-gas over years. An air cleaner
with granular chemisorbant gas phase filter should be chosen.
Off- gassing of carpets tends to be a shorter-term problem,
since it mostly stems from the glue or foam backing in the carpet.
Here the problem ise of a classical VOC issue, where a granular
carbon filter will be suitable. If both are an issue, it best
to choose an air cleaner that combines both activated carbon
and chemisorbant (IQAir MultiGas GC). |
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